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Abstract

In seafood processing plants, industrial waste water discharge reached virtually the level B (QCVN 11-MT:2015/BTNMT) after using mechanical, physicochemical and biological wastewater treatment methods. However, their COD values (COD = 20-120 mg/L) were not qualified for allowable concentration of discharge requirement - level A (COD ≤ 75 mg/L) in many cases. In this paper, bio-treated seafood waster water was continually treated by TiO2 photocatalyst modified by doping Fe and N to degrade recalcitrant organic pollutants to obtain the A level water which can be resused. TiO2 modified by doping Fe and N were prepared and investigated the physico-chemicalproperties. The results showed that modified TiO2 had a lower band gap and more photoactivity than pure TiO2. Beside that, at the reaction conditions: reaction temperature 25 oC, dissolved oxygen concentration 7.6 mg/L and pH = 7, the optimal concentration of catalysts was determined (1.25 g/L). After 12 hours of treatment, COD removal efficiency on TiO2-Fe and TiO2-N catalysts attained 41.1 % and 64.3 %, respectively, and their COD values reached 49.3 and 29.9 mg/L, correspondingly. After treatment, the quality of waste water discharge met the level A (QCVN 11-MT:2015/BTNMT) and became a safety source for reusing (QCVN 08-MT:2015/BTNMT). In addition, the relationship between the characterization of modifed TiO2 and their activity was characterized.



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Issue: Vol 1 No T4 (2017)
Page No.: 241-248
Published: Dec 31, 2017
Section: Original Research
DOI: https://doi.org/10.32508/stdjns.v1iT4.479

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Creative Commons License

Copyright: The Authors. This is an open access article distributed under the terms of the Creative Commons Attribution License CC-BY 4.0., which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

 How to Cite
Luu, L., Ho, D., Hoang, P., Nguyen, T., Nguyen, V., Hoang, C., & Ha, A. (2017). Degradation of recalcitrant organic polluants in seafood wastewater by modified TiO2 photocatalysts. Science and Technology Development Journal - Natural Sciences, 1(T4), 241-248. https://doi.org/https://doi.org/10.32508/stdjns.v1iT4.479

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