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Abstract

ZnCl2 in 1-allyl-3-methylimidazolium trifloromethanesulfonate was found to be a good catalyst for the Friedel-Crafts acylation. The ketone product was isolated easily from the reaction mixture. The reactions were found to proceed smoothly under microwave irradiation. The isolated yield was high with 95% selectivity of pisomer within a few minutes. Moreover, ZnCl2 and ion liquid have been recovered and reused several times without significant loss of catalytic activity.



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Issue: Vol 2 No 1 (2018)
Page No.: 34-39
Published: Jan 6, 2019
Section: Original Research
DOI: https://doi.org/10.32508/stdjns.v2i1.671

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Copyright: The Authors. This is an open access article distributed under the terms of the Creative Commons Attribution License CC-BY 4.0., which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

 How to Cite
Dung, N. T. K., & Phuong, T. H. (2019). Synthesis of ion liquid 1-allyl-3-methylimidazolium trifluoromethanesulfonate and application as green solvent on the Friedel-Crafts acylation. Science and Technology Development Journal - Natural Sciences, 2(1), 34-39. https://doi.org/https://doi.org/10.32508/stdjns.v2i1.671

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